Responsive inks and 3D patterning play a crucial role in the development of next-generation functional materials, enabling precise spatial control over structure and properties. Our research explores advanced fabrication processes for responsive ink systems and 3D patterning through precise control of material assembly and structuring. We develop sophisticated manufacturing platforms using microfluidics, robot dispenser, and bio-3D printer to achieve precise spatial control and complex architectures. These processing techniques enable the controlled fabrication of diverse functional materials, including hydroxypropyl cellulose (HPC), photonic block copolymer particles, and photonic hydrogels. Through optimization of these fabrication strategies, we aim to establish robust protocols for creating programmable and responsive material systems with controlled hierarchical structures.